Step 1:
Run Outlook.
Step 2:
In the Navigation Pane, right-click Personal Folders and then select Properties for "Personal Folders"....

Step 3:
Click Advanced and make a note of the name and location of the file.

Step 1:
If Outlook is open, close it now.
Within Windows Explorer, browse to the location of the PST file (see above).
To do this, within Windows Explorer select Tools from the top menu, then Folder Options.
Click the View tab, and then under Advanced settings select Show hidden files and folders.

Step 2:
Back in Windows Explorer, highlight the PST file, then from the top menu select edit and then cut.
Step 3:
Still within Windows Explorer, browse to a new location where the PST will be stored and select edit and then paste.
Step 4:
Next open the Control Panel and choose Mail.
Step 5:
Click Data Files, highlight the Personal Folders data file, and click Settings

An error dialog box should appear warning that the data file could not be found:

Step 6:
Click OK, browse to the new location of the PST file, select it, and then click Open.
Step 7:
Click OK, then Close, and Close again.
Finally, restart Outlook.
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